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1.
Sébastien Gogo Jean-Baptiste Paroissien Fatima Laggoun-Défarge Jean-Marc Antoine Léonard Bernard-Jannin Guillaume Bertrand Philippe Binet Stéphane Binet Guillaume Bouger Yohann Brossard Thierry Camboulive Jean-Pierre Caudal Stéphane Chevrier Geneviève Chiapiuso Benoît D'Angelo Pilar Durantez Chris Flechard André-Jean Francez Didier Galop Laure Gandois Daniel Gilbert Christophe Guimbaud Louis Hinault Adrien Jacotot Franck Le Moing Emilie Lerigoleur Gaël Le Roux Fabien Leroy Alexandre Lhosmot Qian Li Elodie Machado Da Silva Jean-Sébastien Moquet Juanita Mora-Gomez Laurent Perdereau Thomas Rosset Marie-Laure Toussaint 《水文研究》2021,35(6):e14244
Mitigating and adapting to global changes requires a better understanding of the response of the Biosphere to these environmental variations. Human disturbances and their effects act in the long term (decades to centuries) and consequently, a similar time frame is needed to fully understand the hydrological and biogeochemical functioning of a natural system. To this end, the ‘Centre National de la Recherche Scientifique’ (CNRS) promotes and certifies long-term monitoring tools called national observation services or ‘Service National d'Observation’ (SNO) in a large range of hydrological and biogeochemical systems (e.g., cryosphere, catchments, aquifers). The SNO investigating peatlands, the SNO ‘Tourbières’, was certified in 2011 ( https://www.sno-tourbieres.cnrs.fr/ ). Peatlands are mostly found in the high latitudes of the northern hemisphere and French peatlands are located in the southern part of this area. Thus, they are located in environmental conditions that will occur in northern peatlands in coming decades or centuries and can be considered as sentinels. The SNO Tourbières is composed of four peatlands: La Guette (lowland central France), Landemarais (lowland oceanic western France), Frasne (upland continental eastern France) and Bernadouze (upland southern France). Thirty target variables are monitored to study the hydrological and biogeochemical functioning of the sites. They are grouped into four datasets: hydrology, fluvial export of organic matter, greenhouse gas fluxes and meteorology/soil physics. The data from all sites follow a common processing chain from the sensors to the public repository. The raw data are stored on an FTP server. After operator or automatic processing, data are stored in a database, from which a web application extracts the data to make them available ( https://data-snot.cnrs.fr/data-access/ ). Each year at least, an archive of each dataset is stored in Zenodo, with a digital object identifier (DOI) attribution ( https://zenodo.org/communities/sno_tourbieres_data/ ). 相似文献
2.
Marc Antoine Couillard Gilbert Cabana Jean François Dery Gaétan Daigle Julian John Dodson 《Estuaries and Coasts》2011,34(6):1234-1245
Tomcod (Microgadus tomcod) in the St. Lawrence estuarine transition zone (ETZ) undergo an ontogenetic habitat shift. Older age classes, characterised
by a male-dominated sex ratio, disperse downstream over the summer months to occupy the colder more saline waters of the estuary.
Significant differences in length and mass along the salinity gradient were observed in September with upstream fish of any
given age class generally exhibiting greater growth. These differences were not seen in early summer. Benthic amphipod δ
34S signatures were strongly correlated with salinity and served to demonstrate that tomcod δ
34S signatures were not in isotopic equilibrium in the more saline waters of the ETZ. Seasonal distributional patterns, growth
dynamics and isotopic disequilibrium all indicate that the observed habitat shift may occur on an annual basis, following
winter aggregation in warmer, less saline waters. Tomcod located in the downstream parts of the ETZ, predominantly males,
were significantly more sexually developed than upstream tomcod for a given age. On the other hand, greater growth early in
life is insured by occupying warmer, upstream waters during the summer months. 相似文献
3.
Gilbert J. Price Gregory E. Webb Jian-xin Zhao Yue-xing Feng Andrew S. Murray Bernard N. Cooke Scott A. Hocknull Ian H. Sobbe 《Quaternary Science Reviews》2011,30(7-8):899-914
A key to understanding Late Pleistocene megafaunal extinction dynamics is knowledge of megafaunal ecological response(s) to long-term environmental perturbations. Strategically, that requires targeting fossil deposits that accumulated during glacial and interglacial intervals both before and after human arrival, with subsequent palaeoecological models underpinned by robust and reliable chronologies. Late Pleistocene vertebrate fossil localities from the Darling Downs, eastern Australia, provide stratigraphically-intact, abundant megafaunal sequences, which allows for testing of anthropogenic versus climate change megafauna extinction hypotheses. Each stratigraphic unit at site QML796, Kings Creek Catchment, was previously shown to have had similar sampling potential, and the basal units contain both small-sized taxa (e.g., land snails, frogs, bandicoots, rodents) and megafauna. Importantly, sequential faunal horizons show stepwise decrease in taxonomic diversity with the loss of some, but not all, megafauna in the geographically-small palaeocatchment. The purpose of this paper is to present the results of our intensive, multidisciplinary dating study of the deposits (>40 dates). Dating by means of accelerator mass spectrometry (AMS) 14C (targeting bone, freshwater molluscs, and charcoal) and thermal ionisation mass spectrometry U/Th (targeting teeth and freshwater molluscs) do not agree with each other and, in the case of AMS 14C dating, lack internal consistency. Scanning electron microscopy and rare earth element analyses demonstrate that the dated molluscs are diagenetically altered and contain aragonite cements that incorporated secondary young C, suggesting that such dates should be regarded as minimum ages. AMS 14C dated charcoals provide ages that occur out of stratigraphic order, and cluster in the upper chronological limits of the technique (~40–48 ka). Again, we suggest that such results should be regarded as suspicious and only minimum ages. Subsequent OSL and U/Th (teeth) dating provide complimentary results and demonstrate that the faunal sequences actually span ~120–83 ka, thus occurring beyond the AMS 14C dating window. Importantly, the dates suggest that the local decline in biological diversity was initiated ~75,000 years before the colonisation of humans on the continent. Collectively, the data are most parsimoniously consistent with a pre-human climate change model for local habitat change and megafauna extinction, but not with a nearly simultaneous extinction of megafauna as required by the human-induced blitzkrieg extinction hypothesis. This study demonstrates the problems inherent in dating deposits that lie near the chronological limits of the radiocarbon dating technique, and highlights the need to cross-check previously-dated archaeological and megafauna deposits within the timeframe of earliest human colonisation and latest megafaunal survival. 相似文献
4.
Benoît Thibodeau Moritz F. Lehmann Jacqueline Kowarzyk Alfonso Mucci Yves Gélinas Denis Gilbert Roxane Maranger Mohammad Alkhatib 《Estuarine, Coastal and Shelf Science》2010
Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L−1), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L−1, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m−2 d−1 in the hypoxic western LSLE to 100 μmol m−2 d−1 in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m−2 d−1, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 106 t N, yielding an almost balanced N budget for the SL marine system. 相似文献
5.
6.
The pressure variations during the production of petroleum reservoir induce stress changes in and around the reservoir. Such changes of the stress state can induce marked deformation of geological structures for stress sensitive reservoirs as chalk or unconsolidated sand reservoirs. The compaction of those reservoirs during depletion affects the pressure field and so the reservoir productivity. Therefore, the evaluation of the geomechanical effects requires to solve in a coupling way the geomechanical problem and the reservoir multiphase fluid flow problem. In this paper, we formulate the coupled geomechanical‐reservoir problem as a non‐linear fixed point problem and improve the resolution of the coupling problem by comparing in terms of robustness and convergence different algorithms. We study two accelerated algorithms which are much more robust and faster than the conventional staggered algorithm and we conclude that they should be used for the iterative resolution of coupled reservoir‐geomechanical problem. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
7.
R. Nagendra P. Sathiyamoorthy A. N. Reddy Harry Gilbert B. C. Jaiprakash 《Arabian Journal of Geosciences》2014,7(10):4133-4144
Grey shale Member of the Dalmiapuram Formation, Ariyalur Group, Cauvery Basin, India was studied for its stratigraphic position, age, and paleobathymetry with a re-look into the lithological relationship and foraminifer assemblages in the deepened limestone mine excavations at M/s Dalmia Cements, Dalmiapuram. Twenty grey shale samples from Kovandankurchchi (pit-4) and Kallakkudi mines yielded diversified calcareous, benthic, and rare index planktic foraminifera. The foraminiferal assemblages suggest a latest Albian age and middle neritic depositional conditions. The abundance of kaolinite and smectite clay minerals relate to warm/humid climate which corroborate with rising relative sea level during grey shale deposition. The grey shale occurs in patches within the marl bedded limestone member which exhibits cyclic deposition of limestone and marl. The limestone mine sections demonstrate that the grey shale forms part of basal marl bedded limestone, directly overlying the coral algal limestone. The present study demonstrates that the grey shale outcrops in Dalmiapuram Formation should be placed stratigraphically as part of marl bedded limestone. The member status for grey shale which is current usage stands discounted. 相似文献
8.
Verónica Oliveros Gilbert Féraud Luis Aguirre Luis Ramírez Michel Fornari Carlos Palacios Miguel Parada 《Mineralium Deposita》2008,43(3):281-293
The 40Ar/39Ar geochronological method was applied to date magmatic and hydrothermal alteration events in the Mantos Blancos mining district
in the Coastal Cordillera of northern Chile, allowing the distinction of two separate mineralization events. The Late Jurassic
Mantos Blancos orebody, hosted in Jurassic volcanic rocks, is a magmatic-hydrothermal breccia-style Cu deposit. Two superimposed
mineralization events have been recently proposed. The first event is accompanied by a phyllic hydrothermal alteration affecting
a rhyolitic dome. The second mineralization event is related to the intrusion of bimodal stocks and sills inside the deposit.
Because of the superposition of several magmatic and hydrothermal events, the obtained 40Ar/39Ar age data are complex; however, with a careful interpretation of the age spectra, it is possible to detect complex histories
of successive emplacement, alteration, mineralization, and thermal resetting. The extrusion of Jurassic basic to intermediate
volcanic rocks of the La Negra Formation is dated at 156.3 ± 1.4 Ma (2σ) using plagioclase from an andesitic lava flow. The first mineralization event and associated phyllic alteration affecting
the rhyolitic dome occurred around 155–156 Ma. A younger bimodal intrusive event, supposed to be equivalent to the bimodal
stock and sill system inside the deposit, is probably responsible for the second mineralization event dated at ca. 142 Ma.
Other low-temperature alteration events have been dated on sericitized plagioclase at ca. 145–146, 125, and 101 Ma. This is
the first time that two distinct mineralization events have been documented from radiometric data for a copper deposit in
the metallogenic belt of the Coastal Cordillera of northern Chile.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
9.
10.
Javiera Cervini-Silva Benjamin Gilbert Sirine Fakra Stephan Friedlich Jillian Banfield 《Geochimica et cosmochimica acta》2008,72(10):2454-2464
Highly insoluble Ce-bearing phosphate minerals form by weathering of apatite [Ca5(PO4)3.(OH,F,Cl)], and are important phosphorous repositories in soils. Although these phases can be dissolved via biologically-mediated pathways, the dissolution mechanisms are poorly understood. In this paper we report spectroscopic evidence to support coupling of redox transformations of organic carbon and cerium during the reaction of rhabdophane (CePO4·H2O) and catechol, a ubiquitous biogenic compound, at pH 5. Results show that the oxic–anoxic conditions influence the mineral dissolution behavior. Under anoxic conditions, the release of P and Ce occurs stoichiometrically. In contrast, under oxic conditions, the mineral dissolution behavior is incongruent, with dissolving Ce3+ ions oxidizing to CeO2. Reaction product analysis shows the formation of CO2, polymeric C, and oxalate and malate. The presence of more complex forms of organic carbon was also confirmed. Near edge X-ray absorption fine structure spectroscopy measurements at Ce-M4,5 and C-K absorption edges on reacted CePO4·H2O samples in the absence or presence of catechol and dissolved oxygen confirm that (1) the mineral surface converts to the oxide during this reaction, while full oxidation is limited to the near-surface region only; (2) the Ce valence remains unchanged when the reaction between CePO4·H2O and O2 but in the absence of catechol. Carbon K-edge spectra acquired from rhabdophane reacted with catechol under oxic conditions show spectral features before and after reaction that are considerably different from catechol, indicating the formation of more complex organic molecules. Decreases in intensity of characteristic catechol peaks are accompanied by the appearance of new π* resonances due to carbon in carboxyl (ca. 288.5 eV) and carbonyl (ca. 289.3 eV) groups, and the development of broad structure in the σ* region characteristic of aliphatic carbon. Evolution of the C K-edge spectra is consistent with aromatic-ring cleavage and polymerization. These results further substantiate that the presence of catechol, O2 (aq) causes both the oxidation of structural Ce3+ and the transformation of catechol to more complex organic molecules. Scanning Transmission X-Ray Microscopy measurements at the C K and Ce M4,5 edges indicate three dominant organic species, varying in complexity and association with the inorganic phase. Untransformed catechol is loosely associated with CeO2, whereas more complex organic molecules that exhibit lower aromaticity and stronger CO π* resonances of carboxyl-C and carbonyl-C groups are only found in association with the grains. These results further serve as basis to postulate that, in the presence of O2, CeO2 can mediate the oxidative polymerization of catechol to form higher molecular weight polymers. The present work provides evidence for a pathway of biologically-induced, non-enzymatic oxidation of cerium and formation of small CeO2 particles at room temperature. These findings may have implications for carbon cycling in natural and cerium-contaminated soils and aqueous environments. 相似文献